The Maillard Reaction

The Maillard reaction explained — why steam management, oven temperature, and timing all determine the colour and flavour of the sourdough crust.

BAKING

The Maillard Reaction

Science Notes — number38.com

The crust is the part of the loaf most bakers notice first and understand least. The colour, the crackle, the deep caramel smell coming out of the oven — those are chemistry, not luck. Specifically, they are the Maillard reaction: a chain of chemical events between amino acids and reducing sugars that produces hundreds of flavour compounds.

Understanding this is why steam matters in the first half of the bake, and why you remove it in the second half. The two stages of baking are addressing two entirely different problems: oven spring and crust development. You cannot optimise both simultaneously.

12 BAKING NUMBER38.COM The Maillard Reaction The Maillard reaction is responsible for crust colour, aroma, and flavour development during baking. It is a chemical reaction between amino acids (from protein) and reducing sugars (from starch breakdown), occurring above approximately 140 °C on the crust surface. It is distinct from caramelisation (sugars alone, >160 °C). BAKING STRATEGY: • First 15–20 min: steam traps moisture, crust stays extensible, loaf springs fully before setting. • Steam removed: temperature climbs, Maillard reaction accelerates — crust browns, crackles, and flavours develop. Source: Maillard, 1912 (C. R. Acad. Sci.); Belitz et al., Food Chemistry, 2009

The panel is the last in the series of twelve. Between them, they cover the microbiology, the chemistry, and the technique behind sourdough. The data — the fermentation charts Francis has been building — will follow in a later section of the blog.

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